'DX' is a radio abbreviation for distance. So, 'DXing' means seeing how far you can hear or communicate.
There are lots of reasons why what you can hear changes from day light to dark. Primarily, what you can hear deals with propagation, how a signal 'bounces' off of the ionosphere. And then the fact that some stations decrease/increase output power at various times, and also the direction they happen to be transmitting. Propagation also is frequency dependent, different frequencies propagate (bounce) differently. The color of the grass around a stations transmitting antenna can also be an indication of how well it will be heard, believe it of not! Nothing to do with the grass at all, but with the 'quality' of the electrical ground of the antenna. Moisture tends to make for a 'better' ground, typically, which will change the radiation characteristics of an antenna. (Geeze! Now I gotta worry about the color of grass?)
Ain't all this 'stuff' fun!?
- 'Doc