Why not? Typically because the difference in conductivity is so minuscule that the difference that would be heard is nonexistent. And then the other characteristics of copper may not be suitable for the application, weight and strength for instance. Use whatever is suitable for the situation, be that copper, aluminum, or whatever.
Broadbandedness.
The diameter of the conductor does play a small part in that. But when you're talking about the typical "broadbanded" antennas, the broadbandedness usually results from something else entirely. Rather than try to explain that, go take a look at 'K0BG's web site, it's there and he does a much better job of explaining than I do.
- 'Doc