No. You would need a much more accurate SWR/Peak reading watt meter....Dosy is entry level and not known for accuracy. You would also need a good multimeter, a dummy load, and possibly a basic signal generator as well as a set of plastic alignment tools....metal will shatter the ferrite cores of the coils. Your power supply needs to be well regulated. Of course, you wouldn't attempt such a thing without knowing the actual alignment steps in the correct order!
But beyond all that, no amount of tweaking and tuning is going to make a PC66 sound any louder on receive. You might get another watt or two out of it, but keep in mind that in order for the person hearing you to get 1 more S unit, you would need to quadruple power. You would need to multiply power by 16 to get 2 S units increase. That PC66 might make 5 or 6 watts, but it sure won't do 16 or 64 watts LOL!
If you really want to get out better it is all about the antenna. Whether you are a mobile or a base you want the best antenna you can get. If you've done that and you still have trouble being heard, buy an RM Italy amp.....they're cheap and will give you a boost up to 80 watts or more.